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  8. Metanotricarboxilato de trietilo, 98 %, Thermo Scientific Chemicals

Metanotricarboxilato de trietilo, 98 %, Thermo Scientific Chemicals

Código de producto. 11378105
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Product Code. 11378105 Supplier Thermo Scientific Alfa Aesar Supplier No. L08356.14
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Description

CAS: 6279-86-3 | C10H16O6 | 232.232 g/mol

Methanetricarboxylates have been used as blocked malonic esters, restricting reaction with alkyl halides to monoalkylation. The unwanted carboxyl group can be removed by treatment with Na alkoxide, LDA or BCl3. Provides a useful 2-carbon chain extension method that adds to Michael acceptors under phase-transfer conditions. Triethyl Methanetricarboxylate is used in the synthesis of novel inhibitors of Hsp90. It is also used in the preparation of novel dihydroquinoline-3-carboxylic acids that function as HIV-1 integrase inhibitors.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
Los metanotricarboxilatos se han utilizado como ésteres malónicos «bloqueados», lo que restringe la reacción con los haluros de alquilo para la monoalquilación. El grupo carboxilo no deseado se puede eliminar mediante tratamiento con alcóxido de Na, LDA o BCl3. Proporciona un método útil de extensión de la cadena de 2-carbono que se añade a los aceptores de Michael en condiciones de transferencia de fase. El metanotricarboxilato de trietilo se utiliza en la síntesis de los nuevos inhibidores de Hsp90. También se utiliza en la preparación de los nuevos ácidos de dihidroquinolina-3-carboxílicos que funcionan como inhibidores de la integrasa del VIH-1.

Solubilidad
Insoluble en agua.

Notas
Almacenar alejado de agentes oxidantes. Mantener el recipiente bien cerrado en un lugar fresco, seco y bien ventilado.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 6279-86-3
Fórmula molecular C10H16O6
Peso molecular (g/mol) 232.232
Número MDL MFCD00009150
Clave InChI AGZPNUZBDCYTBB-UHFFFAOYSA-N
Sinónimo tricarbethoxymethane, triethylmethanetricarboxylate, methanetricarboxylic acid, triethyl ester, 2-ethoxycarbonyl-malonic acid diethyl ester, methanetricarboxylic acid triethyl ester, carboxymalonic acid triethyl ester, diethyl 2-ethoxycarbonyl malonate, diethyl 2-ethoxycarbonyl propane-1,3-dioate, pubchem3106, triethoxycarbonylmethane
PubChem CID 80471
Nombre IUPAC metanotricarboxilato de trietilo
SMILES CCOC(=O)C(C(=O)OCC)C(=O)OCC

Specifications

Nombre del producto químico o material Triethyl methanetricarboxylate
Punto de fusión 26°C to 29°C
Densidad 1.095
Punto de ebullición 253°C
Temperatura de inflamación >110°C (230°F)
Índice de refracción 1.4255
Cantidad 25 g
Beilstein 1793645
Información de solubilidad Insoluble in water.
Formula Weight (peso de la fórmula) 232.23
Porcentaje de pureza 98%
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