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Diethyl azodicarboxylate, 97%, Thermo Scientific™
Descripción
Este producto de marca Thermo Scientific formó parte originalmente de la cartera de productos Alfa Aesar. Alguna información sobre documentos y etiquetas puede referirse a la marca original. El producto original Alfa Aesar / código de artículo original o la referencia SKU no ha cambiado como parte de la transición de la marca a Thermo Scientific.
Applications
Diethyl azodicarboxylate acts as a dienophile used in Diels-Alder reactions. It is used as a reagent in alfa-thiocyanation of enolizable ketones with ammonium thiocyanate and annulation of N-protected imines. It acts as a reactant for the preparation of immunostimulants alfa-Galactosylceramides, bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase and aza-beta-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes. It finds application in Mitsunobu reaction and used in the synthesis of pharmaceuticals like zidovudine and procarbazine. The presence of azo group in it is a Michael acceptor and used for the conversion of beta-ketoesters to the corresponding hydrazine derivatives in presence of copper(II) catalyst. Further, it is an efficient dehydrogenating agent, which is involved in the preparation of aldehydes, disulfides from alcohols and thiols respectively.
Solubility
Miscible with dichloromethane, diethyl ether and toluene.
Notes
Store in a cool place. Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.
Diethyl azodicarboxylate acts as a dienophile used in Diels-Alder reactions. It is used as a reagent in alfa-thiocyanation of enolizable ketones with ammonium thiocyanate and annulation of N-protected imines. It acts as a reactant for the preparation of immunostimulants alfa-Galactosylceramides, bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase and aza-beta-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes. It finds application in Mitsunobu reaction and used in the synthesis of pharmaceuticals like zidovudine and procarbazine. The presence of azo group in it is a Michael acceptor and used for the conversion of beta-ketoesters to the corresponding hydrazine derivatives in presence of copper(II) catalyst. Further, it is an efficient dehydrogenating agent, which is involved in the preparation of aldehydes, disulfides from alcohols and thiols respectively.
Solubility
Miscible with dichloromethane, diethyl ether and toluene.
Notes
Store in a cool place. Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.
Especificaciones
Especificaciones
| Nombre del producto químico o material | Diethyl azodicarboxylate |
| Densidad | 1.106 |
| Punto de ebullición | 106°C (13 mmHg) |
| Temperatura de inflamación | 85°C (185°F) |
| Fórmula lineal | CH3CH2O2C-N=N-CO2CH2CH3 |
| Índice de refracción | 1.421 |
| Cantidad | 100 g |
| Número UN | UN2810 |
| Beilstein | 908662 |
| Sensibilidad | Air and light sensitive |
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Título del producto
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