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  6. 5-Norborneno-2-carboxaldehído, endo + exo, 95 %, Thermo Scientific Chemicals

5-Norborneno-2-carboxaldehído, endo + exo, 95 %, Thermo Scientific Chemicals

Código de producto. 11481537
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Product Code. 11481537 Supplier Thermo Scientific Alfa Aesar Supplier No. B24973.14
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Description

CAS: 5453-80-5 | C8H10O | 122.167 g/mol

5-Norbornene-2-carboxaldehyde was used in transition metal-catalyzed synthesis of norbornene-derived homopolymers having pendent t-Boc-protected quinizarin moieties for patterned fluorescence images. It acts as Diels-Alder adduct of acrolein and cyclopentadiene. It can be used as protected form of acrolein, from which the double bond may be liberated by cycloreversion, e.g. in a useful synthesis of 2-vinylimidazole.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
El 5-norborneno-2-carboxaldehído se utilizaba en la síntesis catalizada por metales de transición de homopolímeros derivados del norborneno con fracciones de quinizarina colgantes t-Boc protegidas para imágenes de fluorescencia con patrón. Actúa como aducto Diels-Alder de acroleína y ciclopentadieno. Se puede utilizar como forma protegida de la acroleína, de la que puede liberarse el doble enlace mediante ciclorreversión, por ejemplo, en una síntesis útil de 2-vinilimidazol.

Solubilidad
Inmiscible en agua.

Notas
Almacenar sin contacto con el aire y los agentes oxidantes. Sensible al aire. Almacenénese bajo gas inerte seco.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 5453-80-5
Fórmula molecular C8H10O
Peso molecular (g/mol) 122.167
Número MDL MFCD00167568
Clave InChI AJIBZRIAUXVGQJ-UHFFFAOYSA-N
Sinónimo 5-norbornene-2-carboxaldehyde, bicyclo 2.2.1 hept-5-ene-2-carboxaldehyde, bicyclo 2.2.1 hept-5-ene-2-carbaldehyde, 2-formyl-5-norbornene, 5-formylbicyclohept-2-ene, 5-norbornene-2-carbaldehyde, 5-norbornane-2-carboxaldehyde, bicyclo 2.2.1 hept-2-ene-5-carbaldehyde
PubChem CID 95117
Nombre IUPAC biciclo[2.2.1]hept-2-eno-5-carbaldehído
SMILES C1C2CC(C1C=C2)C=O

Specifications

Nombre del producto químico o material 5-Norbornene-2-carboxaldehyde
Nombre de nota endo + exo
Densidad 1.032
Punto de ebullición 68°C to 70°C (12 mmHg)
Temperatura de inflamación 50°C (122°F)
Olor Characteristic
Índice de refracción 1.491
Cantidad 25 g
Número UN UN1989
Beilstein 1363813
Sensibilidad Air Sensitive
Información de solubilidad Not miscible in water.
Formula Weight (peso de la fórmula) 122.17
Porcentaje de pureza 95%
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