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Alfa Aesar™ 4-Bromobenzonitrile, 98+%

Marca:  Alfa Aesar™ A10914.18

Detalles adicionales : CAS : 623-00-7 Peso : 0.05000kg Transport : UN number : 3439 Chem class : 6.1 Pack group : III

Cantidad. 50g

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Código de producto. 11494293

  • 110.00€ / 50 g


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Descripción

Descripción

Applications
4-Bromobenzonitrile is used as reagents and solvents. Reaction of 2-propanol, 4-bromobenzonitrile, and NaH in the presence of 1.5 mol % Pd2(dba)3 and 3 mol % (S)-(-)2,2′-bis(di-p-tolylphosphino)- 1,1′-binaphthyl at 50°C afforded 4-isopropoxy- benzonitrile in 80% isolated yield. The synthesis of 4-cyanobiphenyl at room temperature in a flow injection microreactor, using a supported catalyst, without the addition of a base gave a product yield of 67±7% (n=6). This was achieved by injecting 4-bromobenzonitrile. The 3-arylation of 2,5-dimethylthiophene with 4-bromopropiophenone, 4-trifluoromethylbromobenzene or 4-bromobenzonitrile gave 3-5 in only 38-50% yields in Palladium-catalysed direct 3-or 4-arylation of thiophene derivatives using aryl bromides.

Solubility
Very slightly soluble in water(0.2g/L). Soluble in alcohol and ether.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Especificaciones

Identificadores de productos químicos

623-00-7
182.02
HQSCPPCMBMFJJN-UHFFFAOYSA-N
12162
C1=CC(=CC=C1C#N)Br
C7H4BrN
MFCD00001811
4-Cyanobromobenzene
4-bromobenzonitrile

Especificaciones

4-Bromobenzonitrile
111°C to 114°C
50g
≥98%
MFCD00001811
2041518
HQSCPPCMBMFJJN-UHFFFAOYSA-N
4-bromobenzonitrile
12162
623-00-7
235°C to 237°C
130°C (266°F)
C7H4BrN
UN3439
4-Cyanobromobenzene
C1=CC(=CC=C1C#N)Br
182.02
182.03
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