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Bromuro de (1,3-dioxolan-2-ilmetil)trifenilfosfonio, 98 %, Thermo Scientific Chemicals

Catalog Number 11476370
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Cantidad:
10 g
50 g
250 g
Este artículo no se puede devolver. Vea la política de devoluciones
52509-14-5
C22H22BrO2P
429.29
MFCD00011966
FRHRVQQUICVJDG-UHFFFAOYSA-M
1,3-dioxolan-2-ylmethyl triphenylphosphonium bromide, 1,3-dioxolan-2-yl methyl triphenylphosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenylphosphanium bromide, phosphonium, 1,3-dioxolan-2-ylmethyl triphenyl-, bromide, 1,3-dioxolan-2-yl methyltriphenylphosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenyl phosphanium bromide, 1,3-dioxolan-2-ylmethyl triphenyl phosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenylphosphine, bromide, acmc-209kzy
2724194
[(1,3-dioxolan-2-yl)methyl]triphenylphosphanium bromide
[Br-].C(C1OCCO1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Este artículo no se puede devolver. Vea la política de devoluciones
52509-14-5
C22H22BrO2P
429.29
MFCD00011966
FRHRVQQUICVJDG-UHFFFAOYSA-M
1,3-dioxolan-2-ylmethyl triphenylphosphonium bromide, 1,3-dioxolan-2-yl methyl triphenylphosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenylphosphanium bromide, phosphonium, 1,3-dioxolan-2-ylmethyl triphenyl-, bromide, 1,3-dioxolan-2-yl methyltriphenylphosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenyl phosphanium bromide, 1,3-dioxolan-2-ylmethyl triphenyl phosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenylphosphine, bromide, acmc-209kzy
2724194
[(1,3-dioxolan-2-yl)methyl]triphenylphosphanium bromide
[Br-].C(C1OCCO1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

It finds its applications as a reagent for Wittig olefinations with introduction of a 1,3-dioxolane moiety. It is applied as a reactant for the preparation of a ratiometric fluorescent probe for specific detection of cysteine over homocysteine and glutathione, for microwave-assisted synthesis of KN-93 as inhibitor of calmodulin kinase II, for the preparation of fluorinated spirobenzofuran piperidines as s1 receptor ligands, in the synthesis and antitumor agents, in regio-selective preparation of indole derivatives via rhodium-catalyzed domino hydroformylation/indolization.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
Se usa como reactivo para las olefinaciones de Wittig con la introducción de una moiedad de 1,3-dioxolano. Se aplica como reactante para la preparación de sondas radiométricas fluorescentes para la detección específica de cisteína sobre homocisteína y glutatión, para la síntesis asistida por microondas de KN-93 como inhibidor de la calmodulina quinasa II, para la preparación de espirobenzofuranos fluorados piperidinas como ligandos receptores de S1, en la síntesis y los agentes antitumorales, en la preparación regio-selectiva de los derivados del indol a través de la hidroformilación/indolización de dominó catalizada por rodio.

Solubilidad
Soluble en agua (20 °C).

Notas
Higroscópico. Almacénese lejos del agua/humedad y de los agentes oxidantes. Almacénese bajo gas inerte. Mantenga el recipiente bien cerrado en un lugar fresco, seco y bien ventilado.
TRUSTED_SUSTAINABILITY
Nombre del producto químico o material (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
Punto de fusión 186°C to 189°C
Cantidad 50 g
Sensibilidad Hygroscopic
Información de solubilidad Soluble in water (20°C).
Formula Weight (peso de la fórmula) 429.3
Porcentaje de pureza 98%

RUO – Research Use Only

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